125553-79-9Relevant academic research and scientific papers
Fluoride ion-induced hydrosilylation of aldehydes and ketones under phase-transfer conditions
Goldberg, Yu.,Abele, E.,Shymanska, M.,Lukevics, E.
, p. C9 - C11 (1989)
The hydrosilylation of aldehydes and ketones with dimethylphenylsilane occurs readily in dichloromethane at room temperature in the presence of catalytic amounts of caesium fluoride and 18-crown-6 to afford silyl ethers of the corresponding aryl and hetar
Hydrosilylation of carbonyl compounds catalysed by alkali metal fluorides in the presence of crown ethers
Goldberg, Yu.,Abele, E.,Shymanska, M.,Lukevics, E.
, p. 127 - 133 (2007/10/02)
Hydrosilylation of the C=O bond with dimethylphenylsilane proceeds readily in low-polarity solvents (dichloromethane, benzene, THF) in the presence of the catalytic pair MF/18-crown-6 (M = Cs, Rb, K), with caesium and rubidium fluorides being the most act
