125554-03-2Relevant academic research and scientific papers
THE SCOPE AND MECHANISM OF REARRANGEMENT OF 4,6-DIALKOXY-2-PYRONES
Venkataraman, Hemalatha,Cha, Jin K.
, p. 3509 - 3512 (2007/10/02)
The scope and mechanism of a remarkably facile interconversation between 4,6-dialkoxy-3-alkyl-2-pyrones and their corresponding 5-alkyl isomers is described.The preponderance of the latter over the former is rationalized by the stereoelectronic conformational preference of the C4-alkoxy group.
