125559-25-3Relevant articles and documents
Reductive Cross Coupling Reaction of a Glyoxylate with Carbonyl Compounds. A Facile Synthesis of α,β-Dihydroxycarboxylate Based on a Low Valent Titanium Compound
Mukaiyama, Teruaki,Sugimura, Hideo,Ohno, Takashi,Kobayashi, Shu
, p. 1401 - 1404 (2007/10/02)
On treatment with a low valent titanium compound, a glyoxylate is reductively converted to the titanium enediolate, which reacts with carbonyl compounds to give the corresponding adducts, α,β-dihydroxycarboxylates, in good yields.