1255651-81-0

Basic information

• Product Name: (R)-methyl 2-(2-(diacetoxyiodo)phenoxy)-3-methylbutanoate
• Synonyms: (R)-methyl 2-(2-(diacetoxyiodo)phenoxy)-3-methylbutanoate
• CAS NO: 1255651-81-0
• Molecular Weight: 452.243
• Mol File: 1255651-81-0.mol

Chemical Properties

• CAS DataBase Reference: (R)-methyl 2-(2-(diacetoxyiodo)phenoxy)-3-methylbutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-methyl 2-(2-(diacetoxyiodo)phenoxy)-3-methylbutanoate(1255651-81-0)
• EPA Substance Registry System: (R)-methyl 2-(2-(diacetoxyiodo)phenoxy)-3-methylbutanoate(1255651-81-0)

Safety Data

• Hazardous Substances Data: 1255651-81-0(Hazardous Substances Data)

Upstream product

• 79-21-0 peracetic acid 
• 1255651-95-6 (R)-methyl 2-(2-iodophenoxy)-3-methylbutanoate 

Downstream Products

• 1291104-90-9 acetic acid (1S,2S)-2-acetoxy-3-methoxy-1-(4-chlorophenyl)propyl ester 
• 1291104-87-4 acetic acid (1S,2S)-2-acetoxy-3-methoxy-1-phenylpropyl ester 
• 1291105-12-8 (1R,2S)-2-acetoxy-1-bromo-3-methoxy-1-phenylpropane 
• 1291104-98-7 (S)-1-(2-chlorophenyl)ethane-1,2-diol-1,2-diacetate 
• 1291104-95-4 acetic acid (1R,2S)-2-acetoxy-3-methoxy-1-(4-chlorophenyl)propyl ester 
• 1291104-91-0 acetic acid (1R,2S)-2-acetoxy-3-methoxy-1-phenylpropyl ester 

Relevant articles and documents

Enantiodifferentiating endo-selective oxylactonization of ortho-alk-l-enylbenzoate with a lactate-derived aryl-λ3-iodane

It's the hype: The asymmetric synthesis of 3-alkyl-4-oxyisochroman-1-one is achieved by oxylactonization of ortho-alk-1-enylbenzoate with a series of optically active hypervalent iodine(III) reagents prepared from lactate or valine as a chiral source (see scheme). The oxylactonization is highly regio-, diastereo-, and enantioselective. 2010 Wiley-VCH Verlag GmbH & Co. KGaA.