125583-07-5Relevant articles and documents
Quasi-solid-state rechargeable lithium-ion batteries with a calix[4]quinone cathode and gel polymer electrolyte
Huang, Weiwei,Zhu, Zhiqiang,Wang, Lijiang,Wang, Shiwen,Li, Hao,Tao, Zhanliang,Shi, Jifu,Guan, Lunhui,Chen, Jun
, p. 9162 - 9166 (2013)
Filled to capacity: Calix[4]quinone (C4Q) has eight available carbonyl groups for binding lithium ions (see picture). It can be exploited to prepare quasi-solid-state rechargeable lithium batteries with a poly(methyl acrylate)/poly(ethylene glycol) based
One Step Synthesis of Calix[n]quinones through the HClO4/PbO2-Mediated Oxidation of Calix[n]arenes
Lavendomme, Roy,Troian-Gautier, Ludovic,Zahim, Sara,Reinaud, Olivia,Jabin, Ivan
, p. 1665 - 1668 (2016)
A procedure using HClO4 and PbO2 allows the straightforward oxidation of para-substituted and unsubstituted calix[n]arenes into the corresponding calix[n]quinones in approximately 82 % yield per quinone unit. These mild conditions constitute a good alternative to the classical procedure that involves highly toxic thallium(III) salts in trifluoroacetic acid.
Syntheses and NMR Behavior of Calixquinone and Calixhydroquinone
Morita, Yutaka,Agawa, Toshio,Nomura, Eisaku,Taniguchi, Hisaji
, p. 3658 - 3662 (2007/10/02)
Calixquinone (7) and calixhydroquinone (6) have been synthesized using three different synthetic pathways.The first pathway to 7 from calixarene (1) consists of six steps: acetylation, Fries rearrangement, Baeyer-Villiger oxidation after acetylat
Syntheses and Crystal Structure of Calixquinone
Morita, Yutaka,Agawa, Toshio,Kai, Yasushi,Kanehisa, Nobuko,Kasai, Nobutami,et al.
, p. 1349 - 1352 (2007/10/02)
Calixquinone and other functionalized calixarenes were synthesized in high yields.The crystal structure of the calixquinone was determined by the X-ray diffraction method.
