1256137-62-8

Basic information

• Product Name: methyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside
• Synonyms: methyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside
• CAS NO: 1256137-62-8
• Molecular Weight: 396.556
• Mol File: 1256137-62-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside(1256137-62-8)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside(1256137-62-8)

Safety Data

• Hazardous Substances Data: 1256137-62-8(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 71117-37-8 (2R,4aR,6R,7R,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 

Downstream Products

• 1256137-72-0 C₂₂H₃₃BrO₇Si 
• 1256138-02-9 C₂₂H₃₂O₇Si 
• 1256137-67-3 methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside 

Relevant articles and documents

Rh(II) carbene-mediated synthesis of methyl α- And β-ketopyranosides: Preparation of carbene precursors, quaternarization of the anomeric position, and ring opening of γ-lactones

Methyl α- and β-ketopyranosides were efficiently prepared by carbene-mediated quaternarization of the anomeric position of corresponding aldopyranosides. Preparation of carbene precursors proved to be tedious and required a two-step procedure involving fi