1256151-93-5Relevant academic research and scientific papers
Development of an improved rhodium catalyst for z-selective anti-markovnikov addition of carboxylic acids to terminal alkynes
Wei, Siping,Pedroni, Julia,Meissner, Antje,Lumbroso, Alexandre,Drexler, Hans-Joachim,Heller, Detlef,Breit, Bernhard
, p. 12067 - 12076 (2013)
To develop more active catalysts for the rhodium-catalyzed addition of carboxylic acids to terminal alkynes furnishing anti-Markovnikov Z enol esters, a thorough study of the rhodium complexes involved was performed. A number of rhodium complexes were cha
Rhodium-catalyzed selective anti -markovnikov addition of carboxylic acids to alkynes
Lumbroso, Alexandre,Vautravers, Nicolas R.,Breit, Bernhard
supporting information; experimental part, p. 5498 - 5501 (2011/02/24)
The selective intermolecular anti-Markovnikov addition of carboxylic acids to terminal alkynes yielding valuable Z-enol esters has been achieved for the first time under rhodium-catalyzed conditions. The catalyst system is applicable to a broad substrate
