1256241-82-3Relevant academic research and scientific papers
Highly chemoselective palladium-catalyzed cross-trimerization between alkyne and alkenes leading to 1,3,5-trienes or 1,2,4,5-tetrasubstituted benzenes with dioxygen
Zhou, Peng,Huang, Liangbin,Jiang, Huanfeng,Wang, Azhong,Li, Xianwei
, p. 8279 - 8282 (2010)
A palladium-catalyzed 1:2 linear/cyclic cross-trimerization of alkyne with alkenes using molecular oxygen as the sole oxidant has been reported for the first time. A series of 1,3,5-trienes and 1,2,4,5-tetrasubstituted benzenes are obtained with high chemoselectivity respectively and mechanisms of these reactions are proposed based on some controlled examination.
