1256242-85-9Relevant academic research and scientific papers
Palladium-catalyzed addition of silyl-substituted chloroalkynes to terminal alkynes
Wada, Tatsuya,Iwasaki, Masayuki,Kondoh, Azusa,Yorimitsu, Hideki,Oshima, Koichiro
, p. 10671 - 10674 (2010)
Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C crosscoupling and aromatic dehalogenation reactions under MW-assisted protocols (see scheme). (Figure Presented)
