1256259-62-7Relevant academic research and scientific papers
Mechanistic insights into the palladium-catalysed asymmetric phosphination of cyclohexenyl triflate
Julienne, Delphine,Delacroix, Olivier,Lohier, Jean-Franaois,De Oliveira-Santos, Jana Sopkova,Gaumont, Annie-Claude
, p. 2489 - 2498 (2011)
Preliminary results on the mechanism of the asymmetricphosphination involving an achiral alkenyl triflate (cyclohexenyl triflate) and a secondary phosphane-borane, (methyl)phenylphosphane-borane (1) are reported. A catalytic cycle is proposed based on the
First study on the enantioselective palladium-catalyzed C-P cross-coupling reaction between an alkenyltriflate and a phosphine-borane
Julienne, Delphine,Delacroix, Olivier,Gaumont, Annie-Claude
experimental part, p. 1099 - 1103 (2011/11/07)
In this article, we report the first example of a palladium-catalyzed asymmetric C-P cross-coupling reaction between a racemic secondary phosphine-borane, methylphenylphosphine-borane 1, and an achiral triflate. The influence of various parameters such as
