1256265-91-4Relevant academic research and scientific papers
Unprecedented reactivity of Iridium(I) secondary phosphine oxide complexes: Formation of P-coordinated phosphinate complexes by P-aryl bond cleavage
Liniger, Marc,Gschwend, Bjoern,Neuburger, Markus,Schaffner, Silvia,Pfaltz, Andreas
, p. 5953 - 5958 (2010)
Aryl-iridium(III) hydride complexes with a P-coordinated phosphinate were formed from [Ir(cod)Cl]2 and secondary phosphine oxide-oxazoline ligands under basic conditions. The structure of these complexes, whose formation involved C-P cleavage, was assigned by X-ray analysis and NMR spectroscopy.
