1256292-35-9Relevant articles and documents
Stable luminescent iridium(III) complexes with bis(N-heterocyclic carbene) ligands: Photo-stability, excited state properties, visible-light-driven radical cyclization and CO2 reduction, and cellular imaging
Yang, Chen,Mehmood, Faisal,Lam, Tsz Lung,Chan, Sharon Lai-Fung,Wu, Yuan,Yeung, Chi-Shun,Guan, Xiangguo,Li, Kai,Chung, Clive Yik-Sham,Zhou, Cong-Ying,Zou, Taotao,Che, Chi-Ming
, p. 3123 - 3136 (2016)
A new class of cyclometalated Ir(iii) complexes supported by various bidentate C-deprotonated (C^N) and cis-chelating bis(N-heterocyclic carbene) (bis-NHC) ligands has been synthesized. These complexes display strong emission in deaerated solutions at roo
Iron-catalyzed tandem cyclization and cross-coupling reactions of iodoalkanes and aryl grignard reagents
Kim, Jae Gon,Son, Young Hoon,Seo, Jin Won,Kang, Eun Joo
, p. 1781 - 1789 (2015)
A range of arylmethyl-substituted pyrrolidines and tetrahydrofurans were produced by FeCl2-catalyzed tandem cyclization and cross-coupling reactions of alkyl iodides and aryl Grignard reagents. The substituents on alkenes had a profound effect
Single-Electron-Transfer Strategy for Reductive Radical Cyclization: Fe(CO)5 and Phenanthroline System
Hwang, Joon Young,Baek, Jong Hwa,Shin, Tae Il,Shin, Jung Ha,Oh, Jae Won,Kim, Kwang Pyo,You, Youngmin,Kang, Eun Joo
, p. 4900 - 4903 (2016/10/18)
An electron-transfer strategy using low-valent iron pentacarbonyl [Fe(CO)5] to generate radical species from alkyl iodides was achieved. A range of pyrrolidines, tetrahydrofurans, and carbocycles were synthesized via 5-exo cyclization reactions of alkyl radical intermediates generated by electron transfer from a system involving Fe(CO)5, 1,10-phenanthroline, and diisopropylamine. Moreover, tandem addition reactions with Michael acceptors were also explored. Photophysical and electrochemical studies support a mechanism that involves electron transfer from the low-valent Fe reductant to alkyl iodide.
Photoredox transformations with dimeric gold complexes
Revol, Guillaume,McCallum, Terry,Morin, Mathieu,Gagosz, Fabien,Barriault, Louis
supporting information, p. 13342 - 13345 (2014/01/06)
Let the sunshine in! Unactivated alkyl and aryl bromides underwent a light-enabled reductive radical cyclization in the presence of a dimeric phosphine-gold complex as a photocatalyst (see scheme; X=C(CO 2Et)2, NR, O). Sunlight can be used as the energy source for this simple and efficient radical reaction, which does not require potentially hazardous and toxic chemical reagents, such as organostannanes and chemical initiators.
Water control over the chemoselectivity of a Ti/Ni multimetallic system: Heck- or reductive-type cyclization reactions of alkyl iodides
Millan, Alba,Alvarez De Cienfuegos, Luis,Miguel, Delia,Campana, Araceli G.,Cuerva, Juan M.
, p. 5984 - 5987 (2013/02/23)
A versatile Ti/Ni multimetallic protocol is described for the efficient catalysis of two different reactions, namely a Heck- and reductive-type cyclization of alkyl iodides, in the absence or presence of water, respectively. Noteworthy, the versatility of
Monolithic and flexible polyimide film microreactors for organic microchemical applications fabricated by laser ablation
Min, Kyoung-Ik,Lee, Tae-Ho,Park, Chan Pil,Wu, Zhi-Yong,Girault, Hubert H.,Ryu, Ilhyong,Fukuyama, Takahide,Mukai, Yu,Kim, Dong-Pyo
experimental part, p. 7063 - 7067 (2010/12/18)
Keeping limber: A monolithic and flexible polyimide film microreactor is introduced for organic reactions and syntheses. Unlike glass microreactors, it is easy to fabricate, yet it is inert to solvents and acids under harsh conditions, unlike other polymer microreactors.