1256359-10-0Relevant articles and documents
Preparation method and application of metal organic ternary cyclic compound
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Paragraph 0026-0027, (2021/04/21)
The invention belongs to the technical field of fine chemical engineering, and relates to a preparation method and application of a metal organic ternary cyclic compound. In the preparation method, L is used as a ligand, Co2+ in transition metal cobalt salt is used as a node for reaction to prepare the metal organic ternary cyclic compound, and the synthesis route is as follows: L + Co2+ to Co-L; the metal organic ternary cyclic compound prepared by the method disclosed by the invention is novel in idea, good in reduction activity, stable in chemical property and easy for large-scale synthesis, so that the metal organic ternary cyclic compound is easier to put into practical application. The yield of the Co-DPD compound in the reaction of reducing 4-[(4-methoxyphenyl) iminomethyl] methyl benzoate into 4-[(4-methoxyphenyl) aminomethyl] methyl benzoate can reach 83%, and the yields of the Co-DPD compound used for preparing 4-[(4-methoxyphenyl) aminomethyl] benzonitrile and N-(4-methoxyphenyl)-4-(trifluoromethyl)-phenylethylamine can reach 95% and 80% respectively.