1256362-36-3

Upstream product

• 1256362-35-2 (3S,6R)-3,6-dihydro-6-(2-((Z)-2-(dimethylphenyl)silyl)-2-(phenylthio)vinyl)-2H-pyran-3-ol 

Downstream Products

• 1256362-38-5 (1R,2R,5S,6S)-5-((S)-1-(phenylsulfonyl)hexan-2-yl)-4,7-dioxabicyclo[4.1.0]heptan-2-ol 
• 1256362-39-6 (1R,2R,5S,6S)-5-((S)-1-(phenylsulfonyl)but-3-en-2-yl)-4,7-dioxabicyclo[4.1.0]heptan-2-ol 
• 1256362-37-4 (1R,2R,5S,6S)-5-((S)-1-(phenylsulfonyl)propan-2-yl)-4,7-dioxabicyclo[4.1.0]heptan-2-ol 
• 1256362-50-1 C₂₄H₃₂O₅Si₂ 
• 1256362-49-8 C₃₀H₃₈O₇SSi₂ 
• 1256362-51-2 C₃₄H₃₄N₂O₉Si₂ 
• 1256362-40-9 (1R,2R,5S,6S)-5-((S)-1-(phenylsulfonyl)but-3-yn-2-yl)-4,7-dioxabicyclo[4.1.0]heptan-2-ol 
• 1256362-55-6 C₂₀H₂₈O₃Si₂ 
• 1256362-52-3 C₂₆H₃₄O₅SSi₂ 

Relevant academic research and scientific papers

Chiral cyclobutane synthesis by exploiting a heteroatom-directed conjugate addition

The syntheses of both enantiomers of cyclobutanes B and ent-B are achieved through heteroatom-directed conjugate addition (HADCA) of nucleophiles to the epoxyvinylsulfone-substituted carbohydrates A and ent-A, which provided carbanions that intramolecularly attacked the epoxide with concomitant formation of the cyclobutane ring.