125640-92-8

Basic information

• Product Name: 2,6-DI-TERT-BUTYL-4-METHYLPHENYLDIAZO ACETATE
• Synonyms: 2,6-DI-TERT-BUTYL-4-METHYLPHENYLDIAZO ACETATE;2,6-Di-tert-Butyl-4-methylphenyldiazo acetate, GC 97%;2,6-Di-tert-butyl-4-methylphenyldiazo acetate,97%
• CAS NO: 125640-92-8
• Molecular Formula: C₁₇H₂₄N₂O₂
• Molecular Weight: 288.38
• Mol File: 125640-92-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: 2,6-DI-TERT-BUTYL-4-METHYLPHENYLDIAZO ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-DI-TERT-BUTYL-4-METHYLPHENYLDIAZO ACETATE(125640-92-8)
• EPA Substance Registry System: 2,6-DI-TERT-BUTYL-4-METHYLPHENYLDIAZO ACETATE(125640-92-8)

Safety Data

• Hazardous Substances Data: 125640-92-8(Hazardous Substances Data)

Usage

Chemical Properties

yellow powder

InChI:InChI=1/C17H24N2O2/c1-11-8-12(16(2,3)4)15(21-14(20)10-19-18)13(9-11)17(5,6)7/h8-10H,1-7H3

Upstream product

• 128-37-0 2,6-di-tert-butyl-4-methyl-phenol 
• 125641-00-1 2,6-Bis(1,1-dimethylethyl)-4-methylphenyl 2-diazo-3-butenoate 

Downstream Products

• 131834-00-9 ((1R,2S)-2-Benzyl-cyclopropyl)-methanol 
• 125641-25-0 2,6-di-tert-butyl-4-methylphenyl trans-2-(n-butyl)cyclopropanecarboxylate 
• 125641-25-0 (1R,2S)-2-Butyl-cyclopropanecarboxylic acid 2,6-di-tert-butyl-4-methyl-phenyl ester 
• 125641-29-4 2,6-di-tert-butyl-4-methylphenyl trans-2-tert-butylcyclopropanecarboxylate 
• 125640-98-4 2,6-di-tert-butyl-4-methylphenyl trans-2-(3-cyclohexen-1-yl)cyclopropanecarboxylate 
• 125641-31-8 2,6-di-tert-butyl-4-methylphenyl anti-6-bicyclo<3.1.0>hexanecarboxylate 
• 125640-94-0 2,6-di-tert-butyl-4-methylphenyl 2-cyclopentenylacetate 
• 131899-82-6 2,6-di-t-butyl-4-methylphenyl trans-(1R,2R)-2-phenylcyclopropane-1-carboxylate 
• 131899-85-9 2,6-di-t-butyl-4-methylphenyl cis-(1R,2S)-2-phenylcyclopropane-1-carboxylate 

Relevant articles and documents

Copper-catalyzed oxyvinylation of diazo compounds

A copper(I)-catalyzed vinylation of diazo compounds with vinylbenziodoxolone reagents (VBX) as partners is reported. The transformation tolerates diverse functionalities on both reagents delivering polyfunctionalized vinylated products. The strategy was successfully extended to a three-component/intermolecular version with alcohols. The obtained products contain synthetically versatile functional groups, such as an aryl iodide, an ester, and an allylic leaving group, enabling further modification.

Low-Temperature Intramolecular [4+2] Cycloaddition of Allenes with Arenes for the Synthesis of Diene Ligands

The intramolecular [4+2] cycloaddition between arenes and allenes first reported by Himbert gives rapid access to rigid polycyclic scaffolds. Herein, we report a one-pot oxyalkynylation/cycloaddition reaction proceeding under mild conditions (23–90 °C) an

Enantioselective Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds

Enantioselective catalytic methods allowing the addition of both a nucleophile and an electrophile onto diazo compounds give a fast access into important building blocks. Herein, we report the highly enantioselective oxyalkynylation of diazo compounds usi