125654-35-5

Upstream product

• 125654-34-4 (2R,3R,6R)-2-Hydroxymethyl-6-phenylsulfanyl-3,6-dihydro-2H-pyran-3-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 111425-52-6 thiophenyl 2,3-dideoxy-α-D-glucopyranoside 

Downstream Products

• 125848-19-3 phenyl-2,4-di-O-acetyl-2,3-dideoxy-1-thio-α-D-threo-hex-2-eno-pyranoside 
• 177263-40-0 N-[(2R,3S,4S,5S,6R)-2-((2R,3R,4S,5R,6S)-4,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydroxy-tetrahydro-pyran-3-yl]-2,2,2-trichloro-acetamide 
• 177263-41-1 N-[(2R,3S,4R,5R,6R)-2-((2R,3R,4S,5R,6S)-4,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydroxy-tetrahydro-pyran-3-yl]-2,2,2-trichloro-acetamide 
• 177263-37-5 N-[(1R,2R,4R,5S,6R)-4-((2R,3R,4S,5R,6S)-4,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,7-dioxa-bicyclo[4.1.0]hept-5-yl]-2,2,2-trichloro-acetamide 
• 177263-33-1 N-[(2R,3S,6S)-2-((2R,3R,4S,5R,6S)-4,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-yl]-2,2,2-trichloro-acetamide 
• 177263-32-0 phenylthio-6-O-tert-butyldimethylsilyl-2,3,4-trideoxy-2-trichloroacetamido-α-D-3-enomannoside 
• 177263-31-9 phenylthio-6-O-tert-butyldimethylsilyl-2,3-dideoxy-4-O-(1-imino-1-trichloromethyl)-α-D-threo-hex-2-enopyranoside 

Relevant academic research and scientific papers

Free-radical reactions of some phenylthio-2,3-dideoxyhex-2-enopyranosides

The free-radical reaction of some phenylthio-2,3-dideoxyhex-2-enopyranosides with allyltri-n-butyl stannane has been studied.

Synthesis of 2-amino-2-deoxy-D-hexopyranoside-containing disaccharides involving glycosylation and [3,3] sigmatropic rearrangement

The syntheses of D-mannosamine 15, D-idosamine 16, D-altrosamine 19, and D-tallosamine 20 derivatives of 2-amino-2-deoxy-D-hexopyranoside-containing disaccharides were achieved by [3,3] sigmatropic rearrangement reaction of the disaccharide 13 having a 4-trichloroacetimidate-2-enoside group, prepared in turn by glycosylation of thioglycosyl donors using Pd(CH3CN)2Cl2-AgOTf as a promoter.