1256543-75-5Relevant academic research and scientific papers
Oxidative oxo Diels-Alder reactions of Baylis-Hillman adducts with electron-rich alkenes in the presence of IBX
Yang, Jing,Li, Heping,Shi, Bo,Tian, Shengzhi,Zhang, Juan
experimental part, p. 1567 - 1576 (2012/05/04)
Baylis-Hillman adducts were oxidized by iodoxybenzoic acid (IBX) to 2-methylene-1,3-dicarbonyl compounds, which can act as oxodiene to react with electron-rich alkenes to generate a variety of oxo Diels-Alder adducts in good yields. Copyright Taylor & Fra
Water mediated trapping of active methylene intermediates generated by IBX-induced oxidation of Baylis-Hillman adducts with nucleophiles
Tan, Jia-Neng,Li, Haoquan,Gu, Yanlong
supporting information; experimental part, p. 1772 - 1782 (2011/02/21)
Water proved to be an efficient solvent for oxidation of a Baylis-Hillman adduct with IBX. The generated product, a methylene intermediate, could be trapped in situ by many nucleophiles in water, such as styrenes, β-dicarbonyl compounds, benzamide and les
