125656-11-3Relevant academic research and scientific papers
The β-Effect: Changing the Ligands on Silicon
Brook, Michael A.,Neuy, Axel
, p. 3609 - 3616 (2007/10/02)
The ability of a silyl group to stabilize a carbocation β to silicon, the β-effect, is directly related to the electron-withdrawing ability of the groups on silicon.This was shown by using the degree of syn addition of bromine to (E)-β-silylstyrenes as a
An Examination of the β-Effect in an Addition Reaction with Different Ligands on Silicon
Brook, Michael A.,Hadi, Mahmud A.,Neuy, Axel
, p. 957 - 959 (2007/10/02)
The degree of cis-addition of bromine to a series of β-silylstyrenes may be used to compare the ability of silicon atoms bearing a variety of different ligands to stabilize a β-carbocation.
