125673-03-2Relevant academic research and scientific papers
Organomolybdenum and Organotungsten Reagents, IV. - About the Chemoselectivity of the Carbonylmethylenating Reagent from 2 MoOCl3(THF)2 and 4 CH3Li
Kauffmann, Thomas,Baune, Juergen,Fiegenbaum, Petra,Hansmersmann, Ursula,Neiteler, Christel,et al.
, p. 89 - 96 (2007/10/02)
From a series of carbonylolefinating Mo complexes the reagent "3", obtained by low-temperature methylation of two equivalents of MoOCl3(THF)2 with four equivalents of methyllithium and warming up, is especially favourable for chemoselective carbonylolefin
Synthesis of olefins from ketones or aldehydes using bis(alkylchloroalumino)methane
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, (2008/06/13)
Ketones or aldehydes are methylenated to form the corresponding olefin by reaction with a bis(alkylchloroalumino)methane, e.g., in the form of its dietherate.
Synthesis of olefins from ketones using bis(alkylchloroalumino)methane
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, (2008/06/13)
Ketones are methylenated to form the corresponding olefin by reaction with a bis(alkylchloroalumino)methane, e.g., in the form of its dietherate.
