1256752-89-2

Upstream product

• 115672-05-4 dimethyl(oxiran-2-yl)(phenyl)silane 
• 1730-25-2 allylmagnesium bromide 
• 156600-00-9 (R)-1-(dimethyl(phenyl)silyl)ethane-1,2-diol 

Downstream Products

• 1256752-94-9 C₂₁H₃₂O₃S₂Si 
• 1256752-95-0 (R,Z)-4-(4-(dimethylphenylsilyl)-2-oxodihydrofuran-3(2H)-ylidene)-2,2-dimethylbutanal 
• 1256752-96-1 (3S,4R)-4-(dimethyl(phenyl)silyl)-3-((1R,2R)-2-hydroxy-3,3-dimethylcyclobutyl)dihydrofuran-2(3H)-one 
• 198758-05-3 (R)-4-(dimethyl(phenyl)silyl)dihydrofuran-2(3H)-one 

Relevant academic research and scientific papers

Copper-Catalyzed Asymmetric Borylallylation of Vinyl Arenes

A copper-catalyzed, enantioselective method for the borylallylation of vinyl arenes is reported. The reaction produces enantioenriched and functionalized organoboron compounds by sequentially incorporating boryl and allyl groups onto the C - C bond of vinyl arenes. Copper-catalyzed borylative coupling of vinyl arenes with allyl phosphates successfully proceeds in a regio- and enantioselective manner in the absence of a palladium cocatalyst.

SmI2-mediated radical cyclizations directed by a C-Si bond

The use of a silicon stereocontrol element in cyclobutanol and cyclopentanol-forming cyclizations mediated by SmI2 results in excellent diastereocontrol. The C-Si bond in the products of cyclization provides a versatile handle for further manip