1256779-00-6

Basic information

• Product Name: [Ni(0)(η2-benzaldehyde-AlMe2(trifluoromethanesulfonate))(PCy3)2]
• CAS NO: 1256779-00-6
• Molecular Weight: 931.803
• Mol File: 1256779-00-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ni(0)(η2-benzaldehyde-AlMe2(trifluoromethanesulfonate))(PCy3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Ni(0)(η2-benzaldehyde-AlMe2(trifluoromethanesulfonate))(PCy3)2](1256779-00-6)
• EPA Substance Registry System: [Ni(0)(η2-benzaldehyde-AlMe2(trifluoromethanesulfonate))(PCy3)2](1256779-00-6)

Safety Data

• Hazardous Substances Data: 1256779-00-6(Hazardous Substances Data)

Upstream product

• 74910-03-5 [Ni(η2-benzaldehyde)(PCy3)2] 

Relevant articles and documents

Nickel(0)-catalyzed formation of oxaaluminacyclopentenes via an oxanickelacyclopentene key intermediate: Me2AlOTf-assisted oxidative cyclization of an aldehyde and an alkyne with nickel(0)

The use of Me2AlOTf as an additive allowed the oxidative cyclization of pivalaldehyde and diphenylacetylene with nickel(0) in the presence of PCy3 to give an oxanickelacyclopentene, the structure of which was unambiguously determined