1256930-64-9

Upstream product

• 1016549-38-4 C₁₁H₁₂N₄O₃ 
• 38064-07-2 phenyl N-hydroxycarbamate 
• 2577-90-4 methyl (2S)-2-amino-3-phenylpropanoate 

Downstream Products

• 1248783-59-6 (S)-5-benzyl-3-hydroxyimidazolidine-2,4-dione 
• 1256930-65-0 (2S,9S)-dimethyl 4,7-dioxo-1,10-diphenyl-5-oxa-3,6,8-triazadecane-2,9-dicarboxylate 
• 26416-38-6 2-[3-(1-methoxycarbonyl-2-phenylethyl)ureido]-3-phenylpropionic acid methyl ester 

Relevant academic research and scientific papers

Efficient Amination of Activated and Non-Activated C(sp3)?H Bonds with a Simple Iron–Phenanthroline Catalyst

A readily available catalyst consisting of iron dichloride in combination with 1,10-phenanthroline catalyzes the ring-closing C?H amination of N-benzoyloxyurea to form imidazolidin-2-ones in high yields. The C?H amination reaction is very general and applicable to benzylic, allylic, propargylic, and completely non-activated aliphatic C(sp3)?H bonds, and it also works for C(sp2)?H bonds. The surprisingly simple method can be performed under open flask conditions.

Different reactivity of hydroxylamine with carbamoyl azides and carbamoyl cyanides: Synthesis of hydroxyureas and carbamoyl amidoximes

The carbamoylating agents carbamoyl azides and carbamoyl cyanides (aka cyanoformamides) react with hydroxylamine in different ways, leading in the first case to N-hydroxyureas and, in the case of carbamoyl cyanides, to carbamoyl amidoxime derivatives. The