125709-81-1

Basic information

• Product Name: Metazachlor-2-hydroxy
• Synonyms: Metazachlor-2-hydroxy
• CAS NO: 125709-81-1
• Molecular Formula: C14H17N3O2
• Molecular Weight: 259.30368
• Mol File: 125709-81-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Metazachlor-2-hydroxy(CAS DataBase Reference)
• NIST Chemistry Reference: Metazachlor-2-hydroxy(125709-81-1)
• EPA Substance Registry System: Metazachlor-2-hydroxy(125709-81-1)

Safety Data

• Hazardous Substances Data: 125709-81-1(Hazardous Substances Data)

Upstream product

• 67129-08-2 Metazachlor 

Relevant articles and documents

ACID CATALYZED HETEROLYSIS OF A PYRAZOL α-CHLOROACETANILIDE DERIVATIVE WITH ALKYL-AMIDONITROGEN FISSION

The base-catalyzed hydrolysis of 2-chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)-acetamide (1) generated 2-hydroxy-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1ylmethyl)-acetamide (2).The acid-catalyzed hydrolysis of compound 1 generated after a short time 2-chloro-N-(2,6-dimethyl)-acetamide (3) and pyrazol (5); after a longer period of time, 4,4'-methylenebis-(2,6-dimethylbenzenamine) (4) and pyrazol (5) were formed; compound 4 was formed by condensation of the non isolated intermediates 2,6-dimethylaniline and formaldehyde.Thus the base-catalyzed hydrolysis of compound 1 did not cleave the amide; the acid-catalyzed one first cleaved the N-amido-alkyl bond; then, the Namido-acyl bond, the hydrolysis products condensing simultaneously together to give the unexpected compound 4.