125720-84-5

Basic information

• Product Name: 2-Propanone, 1-[(1-methylethyl)amino]-3-[2-(2-propenyl)phenoxy]-, oxime, (E)-
• Synonyms: CDDD-1815;(E)-Alprenoxime;1-[2-(2-Propenyl)phenoxy]-3-isopropylaminoacetone (E)-oxime;2-Propanone, 1-[(1-methylethyl)amino]-3-[2-(2-propenyl)phenoxy]-, oxime, (E)- (9CI)
• CAS NO: 125720-84-5
• Molecular Formula: C15H22N2O2
• Molecular Weight: 262.35
• Mol File: 125720-84-5.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 398.7±37.0 °C(Predicted)
• Appearance: /
• Density: 1.02±0.1 g/cm3(Predicted)
• PKA: 11.41±0.10(Predicted)
• CAS DataBase Reference: 2-Propanone, 1-[(1-methylethyl)amino]-3-[2-(2-propenyl)phenoxy]-, oxime, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanone, 1-[(1-methylethyl)amino]-3-[2-(2-propenyl)phenoxy]-, oxime, (E)-(125720-84-5)
• EPA Substance Registry System: 2-Propanone, 1-[(1-methylethyl)amino]-3-[2-(2-propenyl)phenoxy]-, oxime, (E)-(125720-84-5)

Safety Data

• Hazardous Substances Data: 125720-84-5(Hazardous Substances Data)

Upstream product

• 125720-60-7 1-(2-Allyl-phenoxy)-3-isopropylamino-propan-2-one oxime 
• 13707-88-5 alprenolol hydrochloride 

Downstream Products

• 125720-60-7 1-(2-Allyl-phenoxy)-3-isopropylamino-propan-2-one oxime 

Relevant articles and documents

OXIDATION OF ARYLOXYAMINOALCOHOLS WITH ACTIVATED DIMETHYLSULFOXIDE; A NOVEL C-N OXIDATION FACILITATED BY NEIGHBORING GROUP EFFECT

Oxidation of aryloxy-β-aminopropanols (1) with "activated" dimethylsulfoxide (DMSO) was found to provide a convenient "one-pot" method to synthesize aryloxy-β-aminoketo-oximes (3), without isolation of the unstable ketones 2.Assignment of Z and E stereoisomers of oximes 3 was based on 1H- and 13C-NMR studies.Spontaneous isomerisation of 3 was also observed and discussed.Dioxime derivatives 6 and 7 were first isolated as by-products in the oxidation of compounds 1 and an improved synthetic method for 6 was developed.The novel C-N oxidation step involved in the formation of 6 from 1 was rationalized on the basis of neighboring grou p effect.