1257332-37-8Relevant articles and documents
Chiral-at-metal octahedral iridium catalyst for the asymmetric construction of an all-carbon quaternary stereocenter
Chen, Liang-An,Tang, Xiaojuan,Xi, Jianwei,Xu, Weici,Gong, Lei,Meggers, Eric
, p. 14021 - 14025 (2013)
Metal-templated organocatalysis: The enantioselective formation of an all-carbon quaternary stereocenter is catalyzed by the ligand sphere of an inert bis-cyclometalated iridium complex (see picture). In this complex, the metal-centered chirality serves as the sole source for the effective asymmetric induction. Copyright