125783-05-3Relevant articles and documents
Organic reactions in water: An efficient zinc-mediated stereoselective synthesis of (E)- and (Z)-trisubstituted alkenes using unactivated alkyl halides
Das, Biswanath,Banerjee, Joydeep,Mahender, Gurram,Majhi, Anjoy
, p. 3349 - 3352 (2004)
(Chemical Equation Presented) Treatment of the acetyl derivatives of the Baylis-Hillman adducts 3-hydroxy-2-methylene-alkanoates and 3-hydroxy-2- methylene-alkanenitriles with unactivated alkyl halides in the presence of Zn in saturated aqueous NH4/
Highly enantioselective construction of the α-chiral center of amides via iridium-catalyzed hydrogenation of α,β-unsaturated amides
Lu, Wei-Jing,Hou, Xue-Long
supporting information; experimental part, p. 1224 - 1228 (2009/12/06)
The chiral center at the a-position of amides is installed in excellent enantioselectivity via the iridium-catalyzed asymmetric hydrogenation of αβ-unsaturated amides under mild conditions. Even aliphatic amides are suitable substrates. The presence of a
ORGANIC COMPOUNDS
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Page/Page column 50-51, (2008/12/04)
Disclosed are compounds having the ability to modulate, namely to improve, enhance and or modify fragrance compositions due to their ability to inhibit cytochrome P450 enzymes, e.g. CYP2A13 and CYP2B6.
Chemo-, regio- and stereoselective addition of triorganoindium reagents to acetates of Baylis-Hillman adducts: a new strategy for the synthesis of (E)- and (Z)-trisubstituted alkenes
Ranu, Brindaban C.,Chattopadhyay, Kalicharan,Jana, Ranjan
, p. 3847 - 3850 (2008/02/07)
The addition of several trialkyl or triarylindium reagents to the acetates of Baylis-Hillman adducts proceeds readily under the catalysis of copper and palladium derivatives. The reactions of trialkylindiums are catalyzed efficiently by CuI whereas additi
Applications of the Baylis-Hillman Reaction 2: a Simple Stereoselective Synthesis of (E)- and (Z)-Trisubstituted Alkenes
Basavaiah, Deevi,Sarma, Pakala K. S.,Bhavani, Anagani K. D.
, p. 1091 - 1092 (2007/10/02)
Reaction of Grignard reagents with methyl 3-acetoxy-2-methylenealkanoates produces (2E)-2-substituted alk-2-enoates, whereas a similar reaction with 3-acetoxy-2-methylenealkanenitriles provides (2Z)-2-substituted alk-2-enenitriles in high (Z)-stereoselectivity.
