1258012-12-2

Basic information

• Product Name: Ru(C₅H₅)(CH₃CN)(C₉H₆NOP(C₆H₅)2)⁽¹⁺⁾*PF₆^(1-)=Ru(CH₃CN)(C₅H₅)(C₉H₆NOP(C₆H₅)2)PF₆
• CAS NO: 1258012-12-2
• Molecular Weight: 681.519
• Mol File: 1258012-12-2.mol

Chemical Properties

• CAS DataBase Reference: Ru(C₅H₅)(CH₃CN)(C₉H₆NOP(C₆H₅)2)⁽¹⁺⁾*PF₆^(1-)=Ru(CH₃CN)(C₅H₅)(C₉H₆NOP(C₆H₅)2)PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: Ru(C₅H₅)(CH₃CN)(C₉H₆NOP(C₆H₅)2)⁽¹⁺⁾*PF₆^(1-)=Ru(CH₃CN)(C₅H₅)(C₉H₆NOP(C₆H₅)2)PF₆(1258012-12-2)
• EPA Substance Registry System: Ru(C₅H₅)(CH₃CN)(C₉H₆NOP(C₆H₅)2)⁽¹⁺⁾*PF₆^(1-)=Ru(CH₃CN)(C₅H₅)(C₉H₆NOP(C₆H₅)2)PF₆(1258012-12-2)

Safety Data

• Hazardous Substances Data: 1258012-12-2(Hazardous Substances Data)

Upstream product

• 912349-10-1 8-(diphenylphosphanyl-oxy)quinoline 

Relevant articles and documents

Synthesis and characterization of iron and ruthenium complexes bearing P-N ligands based on 8-hydroxyquinoline

The synthesis of bidentate aminophosphine ligands (PNquin) based on 8-hydroxyquinoline is described. These ligands react with cis-Fe(CO) 4Br2 to give selectively octahedral complexes of the type cis,cis-Fe(PNquin)(CO)2Br2. There is only one isomer formed where the two CO and the two bromide ligands adopt a cis configuration. The reaction of [RuCp(CH3CN)3]PF 6 with PNquin ligands affords the halfsandwich complexes [RuCp(PNquin)(CH3CN)]PF6 in high isolated yields. Likewise, treatment of [Ru(η6-p-cymene)(μ-Cl)Cl] 2 with PNquin in the presence of AgCF3SO 3 affords halfsandwich complexes of the type [Ru(η6-p- cymene)(PNquin)Cl]CF3SO3. All ligands and complexes are characterized by NMR and IR spectroscopy. The X-ray structure of representative compounds is reported. In addition, the relative stability of isomeric structures and conformers of Fe(PNquin-Ph)(CO) 2Br2 is studied by means of DFT calculations.