1258064-32-2Relevant academic research and scientific papers
Diastereoselective construction of new 5a-substituted carbaallose by exo-β-selective conjugate addition to endo-exo cross-conjugated cyclohexadienone as key reaction
Fujishima, Takashi,Kitoh, Fukashi,Yano, Tomotsugu,Irie, Ryo
, p. 2279 - 2282 (2010)
Practical synthesis of a new chiral endo-exo cross-conjugated cyclohexadienone was achieved, and its synthetic utility was illustrated by highly exo-β-selective conjugate addition with various nucleophiles. Further diastereoselective transformation of the adduct to an unprecedented 5a-substituted carbaallose is also described. Georg Thieme Verlag Stuttgart - New York.
