1258282-05-1

Basic information

• Product Name: 3-methoxybenzyl 2-deoxy-2-iodo-3,4,6-tri-O-acetyl-α-D-glucopyranoside
• Synonyms: 3-methoxybenzyl 2-deoxy-2-iodo-3,4,6-tri-O-acetyl-α-D-glucopyranoside
• CAS NO: 1258282-05-1
• Molecular Weight: 536.318
• Mol File: 1258282-05-1.mol

Chemical Properties

• CAS DataBase Reference: 3-methoxybenzyl 2-deoxy-2-iodo-3,4,6-tri-O-acetyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methoxybenzyl 2-deoxy-2-iodo-3,4,6-tri-O-acetyl-α-D-glucopyranoside(1258282-05-1)
• EPA Substance Registry System: 3-methoxybenzyl 2-deoxy-2-iodo-3,4,6-tri-O-acetyl-α-D-glucopyranoside(1258282-05-1)

Safety Data

• Hazardous Substances Data: 1258282-05-1(Hazardous Substances Data)

Upstream product

• 6971-51-3 3-methoxybenzyl alcohol 
• 2873-29-2 D-glucal triacetate 

Relevant articles and documents

Bronsted Acids of Anionic Chiral Cobalt(III) Complexes as Catalysts for the Iodoglycosylation or Iodocarboxylation of Glycals

Bronsted acids of anionic chiral Co(III) complexes were found to act as efficient phase-transfer catalysts for the diastereoselective iodoglycosylation or iodocarboxylation of glycals with a variety of alcohols or carboxylic acids, respectively, with N -iodosuccinimide as the iodo cation source. The corresponding 2-deoxy-2-iodoglycosides, including monosaccharides and disaccharides, and 2-deoxy-2-iodoglycosyl carboxylates, which are of high synthetic and biological importance, were obtained in high yields (up to 88%) with good diastereoselectivities (up to 9:1 dr).

An efficient method for the selective synthesis of 2-deoxy-2-iodo- glycosides by O-glycosidation of d-glucal using I2-Cu(OAc) 2

An efficient and convenient method for the synthesis of 2-deoxy-2-iodo-O-glycosides from tri-O-acetyl-d-glucal with various alcohols by using I2-Cu(OAc)2 is described. The 21 examples of corresponding glycosides were obtained in high

Convertible formation of different glycoside using molecular iodine

The observation of convertible formation between 2-deoxy-2-iodo-O- glycosides and 2,3-unsaturated glycoside was described. The selective formation of 2-deoxy-2-iodo-O-glycosides was found from the reaction of D-glucal with iodine in the excess alcohol acceptor or the addition of ceric ammonium nitrate as additive while the addition of a stoichiometric amount of alcohol in solvent favored 2,3-unsaturated glycosides formation. The Japan Institute of Heterocyclic Chemistry.