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1258328-05-0

O-(4-phenylphenyl) N-methyl-N-phenyl thiocarbamate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1258328-05-0 Structure

  • Basic information

    1. Product Name: O-(4-phenylphenyl) N-methyl-N-phenyl thiocarbamate
    2. Synonyms: O-(4-phenylphenyl) N-methyl-N-phenyl thiocarbamate
    3. CAS NO:1258328-05-0
    4. Molecular Formula:
    5. Molecular Weight: 319.427
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1258328-05-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: O-(4-phenylphenyl) N-methyl-N-phenyl thiocarbamate(CAS DataBase Reference)
    10. NIST Chemistry Reference: O-(4-phenylphenyl) N-methyl-N-phenyl thiocarbamate(1258328-05-0)
    11. EPA Substance Registry System: O-(4-phenylphenyl) N-methyl-N-phenyl thiocarbamate(1258328-05-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1258328-05-0(Hazardous Substances Data)

1258328-05-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1258328-05-0 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,2,5,8,3,2 and 8 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1258328-05:
(9*1)+(8*2)+(7*5)+(6*8)+(5*3)+(4*2)+(3*8)+(2*0)+(1*5)=160
160 % 10 = 0
So 1258328-05-0 is a valid CAS Registry Number.

1258328-05-0Relevant articles and documents

Metal-free transformation of phenols into substituted benzamides: A highly selective radical 1,2-O→C transposition in O-aryl-N-phenylthiocarbamates

Baroudi, Abdulkader,Flack, Phillip,Alabugin, Igor V.

, p. 12316 - 12320 (2010)

Radical merry-go-round: A highly efficient metal-free transformation of phenols into benzamides is designed through one-step conversion of phenols to aryl thiocarbamates and a subsequent radical addition/rearrangement/ fragmentation cascade. Computational analysis fully rationalizes the experimentally observed selectivity. Despite the possible competition from N-C fragmentation and N-neophyl rearrangement, the transformation exclusively follows the most kinetically and thermodynamically favored O-neophyl rearrangement path.

DIRECT CONVERSION OF PHENOLS INTO AMIDES AND ESTERS OF BENZOIC ACID

-

Page/Page column 15; 20, (2011/10/12)

A method is provided for the preparation of an aromatic carboxylic acid aryl ester or an N-aryl aromatic carboxamide. The method comprises contacting an O,O-diaryl thiocarbonate or an O-aryl-N-aryl thiocarbamate with a reactant that regioselectively reacts with sulfur, which contact causes an O-neophyl rearrangement, thereby forming either the aromatic carboxylic acid aryl ester or the N-aryl aromatic carboxamide, respectively.

Radical OfC transposition: A metal-free process for conversion of phenols into benzoates and benzamides

Baroudi, Abdulkader,Alicea, Jeremiah,Flack, Phillip,Kirincich, Jason,Alabugin, Igor V.

experimental part, p. 1521 - 1537 (2011/06/11)

We report a metal-free procedure for transformation of phenols into esters and amides of benzoic acids via a new radical cascade. Diaryl thiocarbonates and thiocarbamates, available in a single high-yielding step from phenols, selectively add silyl radicals at the sulfur atom of the CdS moiety. This addition step, analogous to the first step of the Barton-McCombie reaction, produces a carbon radical which undergoes 1,2 OfC transposition through an O-neophyl rearrangement. The usually unfavorable equilibrium in the reversible rearrangement step is shifted forward via a highly exothermic C-S bond scission in the O-centered radical, which furnishes the final benzoic ester or benzamide product. The metal-free preparation of benzoic acid derivatives from phenols provides a potentially useful alternative to metal-catalyzed carbonylation of aryl triflates.

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