1258841-18-7Relevant academic research and scientific papers
Reactivity of Cr(III) μ-oxo compounds: Catalyst regeneration and atom transfer processes
MacLeod, K. Cory,Patrick, Brian O.,Smith, Kevin M.
, p. 688 - 700 (2012/03/07)
Oxidation of CpCr[(XylNCMe)2CH] (Xyl = 2,6-Me2C 6H3) with pyridine N-oxide or air generated the μ-oxo dimer, {CpCr[(XylNCMe)2CH]}2(μ-O). The μ-oxo dimer was converted to paramagnetic Cr(III
Chromium-catalyzed radical cyclization of bromo and chloro acetals
MacLeod, K. Cory,Patrick, Brian O.,Smith, Kevin M.
, p. 6639 - 6641 (2011/02/27)
Cyclopentadienyl chromium β-diketiminate catalysts are used for the radical cyclization of bromo and chloro acetals. Mn powder activated with PbBr2 or PbCl2 is the stoichiometric reductant, and γ-terpinene is the hydrogen atom donor.
