1258859-29-8

Basic information

• Product Name: Tetrakis[4-(1H-imidazol-1-yl)-phenyl]methane
• Synonyms: Tetrakis[4-(1H-imidazol-1-yl)-phenyl]methane;Tetrakis[4-(1-imidazolyl)phenyl]methane
• CAS NO: 1258859-29-8
• Molecular Formula: C₃₇H₂₈N₈
• Molecular Weight: 584.67182
• Mol File: 1258859-29-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 805.8±65.0 °C(Predicted)
• Appearance: /
• Density: 1.25±0.1 g/cm3(Predicted)
• PKA: 5.95±0.10(Predicted)
• CAS DataBase Reference: Tetrakis[4-(1H-imidazol-1-yl)-phenyl]methane(CAS DataBase Reference)
• NIST Chemistry Reference: Tetrakis[4-(1H-imidazol-1-yl)-phenyl]methane(1258859-29-8)
• EPA Substance Registry System: Tetrakis[4-(1H-imidazol-1-yl)-phenyl]methane(1258859-29-8)

Safety Data

• Hazardous Substances Data: 1258859-29-8(Hazardous Substances Data)

Usage

General Description

Tetrakis[4-(1H-imidazol-1-yl)-phenyl]methane is a chemical compound with potential applications in coordination chemistry and catalysis. It is a tetrahedral molecule composed of a central carbon atom bonded to four identical phenyl groups, each of which has an imidazole ring attached. This unique structure gives the compound a high degree of rigidity and stability, making it useful as a ligand for coordinating with metal ions in various chemical reactions. It has also been studied for its potential as a catalyst in organic synthesis and other chemical transformations. Overall, Tetrakis[4-(1H-imidazol-1-yl)-phenyl]methane has shown promise as a versatile and valuable compound for a range of applications in the field of chemistry.

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Relevant articles and documents

Synthesis of two coordination polymer photocatalysts and significant enhancement of their catalytic photodegradation activity by doping with Co2+ Ions

The coordination polymers (CPs) [Zn2(tipm)(1,3-BDC)2] (1) and [Co2(tipm)(1,3-BDC)2]·0.5CH3CN (2·0.5CH3CN) were synthesized by the reactions of Zn(NO3)2 or Co(NO3

Identifying the Recognition Site for Selective Trapping of 99TcO4- in a Hydrolytically Stable and Radiation Resistant Cationic Metal-Organic Framework

Effective and selective removal of 99TcO4- from aqueous solution is highly desirable for both waste partitioning and contamination remediation purposes in the modern nuclear fuel cycle, but is of significant challenge. We report here a hydrolytically stable and radiation-resistant cationic metal-organic framework (MOF), SCU-101, exhibiting extremely fast removal kinetics, exceptional distribution coefficient, and high sorption capacity toward TcO4-. More importantly, this material can selectively remove TcO4- in the presence of large excesses of NO3- and SO42-, as even 6000 times of SO42- in excess does not significantly affect the sorption of TcO4-. These superior features endow that SCU-101 is capable of effectively separating TcO4- from Hanford low-level waste melter off-gas scrubber simulant stream. The sorption mechanism is directly unraveled by the single crystal structure of TcO4--incorporated SCU-101, as the first reported crystal structure to display TcO4- trapped in a sorbent material. A recognition site for the accommodation of TcO4- is visualized and is consistent with the DFT analysis results, while no such site can be resolved for other anions.