1258964-48-5

Basic information

• Product Name: Chloro(pentaMethylcyclopentadienyl){5-Methoxy-2-{1-[(4-Methoxyphenyl)iMino-kN]ethyl}phenyl-kC}iridiuM(III), 99% Iridicycle-MeO
• Synonyms: Chloro(pentaMethylcyclopentadienyl){5-Methoxy-2-{1-[(4-Methoxyphenyl)iMino-kN]ethyl}phenyl-kC}iridiuM(III), 99% Iridicycle-MeO;Chloro(5-methoxy-2-{1-[(4-methoxyphenyl)imino-N]ethyl}phenyl-C)(1,2,3,4,5-pentamethylcyclopentadienyl)iridium(III);Chloro[5-methoxy-2-[1-[(4-methoxyphenyl)imino-N]ethyl]phenyl- C][(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopenta dien-1-yl]iridium
• CAS NO: 1258964-48-5
• Molecular Formula: C26H31ClIrNO2
• Molecular Weight: 617.21
• EINECS: 200-838-9
• Mol File: 1258964-48-5.mol
• Article Data: 1

Chemical Properties

• Melting Point: 200-239°C
• Appearance: orange/Powder
• CAS DataBase Reference: Chloro(pentaMethylcyclopentadienyl){5-Methoxy-2-{1-[(4-Methoxyphenyl)iMino-kN]ethyl}phenyl-kC}iridiuM(III), 99% Iridicycle-MeO(CAS DataBase Reference)
• NIST Chemistry Reference: Chloro(pentaMethylcyclopentadienyl){5-Methoxy-2-{1-[(4-Methoxyphenyl)iMino-kN]ethyl}phenyl-kC}iridiuM(III), 99% Iridicycle-MeO(1258964-48-5)
• EPA Substance Registry System: Chloro(pentaMethylcyclopentadienyl){5-Methoxy-2-{1-[(4-Methoxyphenyl)iMino-kN]ethyl}phenyl-kC}iridiuM(III), 99% Iridicycle-MeO(1258964-48-5)

Safety Data

• Hazard Codes: Xn
• Statements: 40
• Safety Statements: 23-24/25-36/37
• WGK Germany: 3
• Hazardous Substances Data: 1258964-48-5(Hazardous Substances Data)

Usage

Reaction

A versatile catalyst for reductive amination by hydrogen transfer. Acceptorless dehydrogenation of nitrogen heterocycles with a versatile iridium catalyst.

Uses

Catalyst for greener amine synthesis by transfer hydrogenation of imines.A Versatile Catalyst for Reductive Amination by Transfer HydrogenationFormal anti-Markovnikov hydroamination of terminal olefins

General Description

This product has been enhanced for catalytic efficiency.

Upstream product

• 12354-84-6 bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 
• 6325-62-8 N,1-bis(4-methoxyphenyl)ethan-1-imine 

Relevant articles and documents

Highly efficient transformation of levulinic acid into pyrrolidinones by iridium catalysed transfer hydrogenation

Levulinic acid (LA) is transformed into pyrrolidinones via iridium-catalysed reductive amination using formic acid as the hydrogen source under aqueous conditions. The catalytic system is the most active and performs under the mildest conditions ever reported for the reductive amination of LA.