1258965-54-6Relevant articles and documents
Total synthesis and determination of the absolute configuration of (-)-dolabriferol
Laclef, Sylvain,Turks, Maris,Vogel, Pierre
supporting information; experimental part, p. 8525 - 8527 (2011/01/05)
A reaction cascade combining sulfur dioxide with a 1-oxy-1,3-diene and (E)-silyl enol ether formed the basis of a short total synthesis of (-)-dolabriferol (see scheme; TMS=trimethylsilyl). The absolute configuration of this natural product, which was first extracted from a gastropod mollusc in 1996, was established unequivocally.