1259091-81-0Relevant articles and documents
Montmorillonite K-10 catalyzed Mannich reaction: Synthesis of aminonaphthoquinone derivatives from Lawsone
Jayashree, Sankaranarayanan,Shivashankar, Kalegowda
, p. 1805 - 1815 (2018)
An efficient one-pot protocol for the synthesis of 2-((substituted amino)(4-phenyl)methyl)-3-hydroxy-naphthalene-1,4-dione derivatives has been developed by the three-component reaction of 2-hydroxy-naphthalene-1,4-dione, aromatic aldehydes and anilines/heterocyclic amines using montmorillonite K-10 as a catalyst. The advantages of this method include short reaction time, excellent yield and easy work-up.
Design and characterization of Dendrimer of MNPs as a novel, heterogeneous and reusable nanomagnetic organometallic catalyst for one-pot synthesis of hydroxyl naphthalene-1,4-dione derivatives under solvent-free conditions
Mollazehi, Fouziyeh,Shaterian, Hamid Reza
, (2017/12/26)
A novel super acidic magnetic nanoparticle as catalyst was successfully synthesized. The preparation of this dendrimer sulfonic acid functionalized γ-Fe2O3 magnetic core-shell silica nanoparticles as a new recoverable and heterogeneous nanocatalyst was described. The new catalyst was characterized using various techniques such as scanning electron microscopy (SEM), energy dispersive spectrum (EDS), and thermo gravimetric synthesis (TGA). Moreover, we have examined the catalytic activity of the catalyst for one-pot, efficient and facile synthesis of 2-hydroxy-1,4-naphthoquinone derivatives via a three-component condensation reaction of 2-hydroxynaphthalene-1,4-dione, aromatic aldehydes and aniline derivatives. High yields of products, short reaction times, waste-free, mild, ambient and solvent-free reaction conditions are advantages of this protocol. Also, the catalyst can be easily recovered by an external magnetic and reused several times without significant loss of its catalytic activity.
Synthesis of 2-hydroxy-1,4-naphthoquinone derivatives via a three-component reaction catalyzed by nanoporous MCM-41
Shaabani, Soroush,Naimi-Jamal, Mohammad Reza,Maleki, Ali
, p. 46 - 49 (2015/07/07)
A one-pot procedure for synthesis of hydroxyl naphthalene-1,4-dione derivatives via a three-component reaction of 2-hydroxynaphthalene-1,4-dione, aromatic aldehydes and heterocyclic or carbocyclic amines is developed. MCM-41 nanoporous catalyst is effective, easy recovery, reusable and makes work-up easy. This approach is clean and environmentally friendly. The structures of the new compounds were confirmed by FT-IR, 1H NMR, 13C NMR, and elemental analysis.
Synthesis of fluorescent hydroxyl naphthalene-1,4-dione derivatives by a three-component reaction in water
Dabiri, Minoo,Tisseh, Zeinab Noroozi,Bazgir, Ayoob
experimental part, p. 63 - 69 (2011/07/07)
An efficient one-pot synthesis of fluorescent hydroxyl naphthalene-1,4- dione derivatives by a simple, atom-economical and three-component reaction of 2- hydroxynaphthalene-1,4-dione, aromatic aldehydes and heterocyclic or carbocyclic amines in the presence of a catalytic amount of InCl3 in refluxing water is reported. The structures of the compounds were confirmed by IR, 1H NMR, 13C NMR, and elemental analysis. UV- visible absorption coefficient, maximum wavelength and fluorescence emission wavelength were measured in methanol. The products were fluorescent in solution emitting at green light (546-560 nm). The advantages of this procedure are mild reaction conditions, high yields of products, operational simplicity and easy work-up procedures. The workup of these very clean reactions involves only a filtration and simple washing step with EtOH.
