1259100-45-2Relevant articles and documents
Non-coordinating-Anion-Directed Reversal of Activation Site: Selective C?H Bond Activation of N-Aryl Rings
Wang, Dawei,Yu, Xiaoli,Xu, Xiang,Ge, Bingyang,Wang, Xiaoli,Zhang, Yaxuan
, p. 8663 - 8668 (2016/07/07)
An Rh-catalyzed selective C?H bond activation of diaryl-substituted anilides is described. In an attempt to achieve C?H activation of C-aryl rings, we unexpectedly obtained an N-aryl ring product under non-coordinating anion conditions, whereas the C-aryl
Rhodium(III)-catalyzed internal oxidative coupling of N-hydroxyanilides with alkenes via C-H activation
Wen, Jing,Wu, An,Chen, Pei,Zhu, Jin
, p. 5282 - 5286 (2015/08/26)
Abstract Described herein is an efficient new method for ortho-olefination of anilides in the presence of AgSbF6 and NaOAc via rhodium(III)-catalyzed internal oxidative C-H bond activation based on hydroxyl as directing and oxidative group. A range of alkenes and functional groups on acetanilides is supported and a possible mechanism is proposed according to the experimental results.
Highly effective Pd-catalyzed ortho olefination of acetanilides: Broad substrate scope and high tolerability
Kim, Byung Seok,Jang, Chungsik,Lee, Dong Jin,Youn, So Won
, p. 2336 - 2340 (2011/06/25)
Bring it on! An effective Pd-catalyzed ortho olefination of various acetanilides has been developed. This transformation has a broad substrate scope and wide functional-group tolerability, regardless of the electronic and steric properties of acetanilide substrates, providing a straightforward access to highly functionalized arenes.
