1259130-37-4Relevant articles and documents
A heterobimetallic Ni/La-salan complex for catalytic asymmetric decarboxylative 1,4-addition of malonic acid half-thioester
Furutachi, Makoto,Mouri, Shinsuke,Matsunaga, Shigeki,Shibasaki, Masakatsu
, p. 2351 - 2354 (2011/06/25)
Not salen, but salan: A new dinucleating salan-type ligand 1 was developed for the enantioselective decarboxylative 1,4-addition of malonic acid half-thioester to nitroalkenes. A Ni/La/1 complex gave products in 99-40% yield and 94-66% ee.