125916-16-7Relevant academic research and scientific papers
UNEXPECTED REACTIVITY OF HYPERVALENT ANIONIC SPECIES AS ELECTRON ACCEPTORS
Cerveau, G.,Chuit, C.,Corriu, R. J. P.,Gerbier, L.,Reye, C.
, p. 115 - 122 (2007/10/02)
The unexpected beheviour of hypervalent anionic silicon (and germanium) species in the presence of some nucleophilic reagents involving a possible single electron transfer process is described.This capacity to accept electrons depends on both constituents of the complexes (ligand central atom (Si or Ge), cation associated to the complex) and the nature of the reagents (PhCH2MgBr, Cp(CO)2FeNa, Li/Me3SiCl/THF system).
