1259375-05-7Relevant academic research and scientific papers
Study on the reactions of 3-bromo-4-ethoxy-1,1,1-trifluoro-3-buten-2-one with benzenethiols promoted by InCl3?4H2O
Zhao, Jingwei,Song, Tao,Jiang, Huiling,Xu, Liangzhong,Zhu, Shizheng
scheme or table, p. 1623 - 1629 (2011/07/07)
In the presence of InCl3?4H2O, the reaction of 3-bromo-4-ethoxy-1,1,1-trifluoro-3-buten-2-one 2 with a series of benzenethiols proceeds readily and gave both the addition-elimination product 3-bromo-1,1,1-trifluoro-4-thiophenyl-but-3-en-2-one and substitution product 1,1,1-trifluoro-3,4-bis-thiophenyl-but-3-en-2-one. The reactivity of benzenethiols is discussed in terms of their substituted group.
