1259526-75-4Relevant academic research and scientific papers
Synthesis and crystal structure of a dioxovanadium(V) complex with Schiff base derived from 2-[1-(2-aminocyclohexylimino)ethyl]phenol
Ma, Yu-Ping,You, Zhong-Lu
, p. 581 - 584 (2010)
A new dioxovanadium(V) complex, [VO2L]22CH3OH, where L is the deprotonated form of 2-[1-(2-aminocyclohexylimino) ethyl]phenol, has been synthesized and characterized by I.R. spectra and single crystal X-ray diffraction. The compound consists of a centrosymmetric dinuclear dioxovanadium complex molecule and two methanol molecules of crystallization. Each V atom in the complex is six-coordinated through three bonds to oxo groups and through bonds to the tridentate Schiff base ligand, forming an octahedral geometry. The Vm·V distance is 3.188(2) . In the crystal structure, the dioxovanadium complex molecules are linked with the methanol molecules through intermolecular N Hm·O and O-Hm·O hydrogen bonds, forming chains running along the b axis. Copyright Taylor & Francis Group, LLC.
