1259947-83-5Relevant academic research and scientific papers
Nucleophilic Activation of Hydrosilanes via a Strain-Imposing Strategy Leading to Functional Sila-aromatics
Ikeuchi, Toshiya,Hirano, Keiichi,Uchiyama, Masanobu
, p. 4879 - 4885 (2021)
Carefully designed cyclic hydrosilanes enable trans-selective hydrosilylation of unactivated alkynes without transition metal catalysts via silicate formation. Employment of sterically demanding bidentate ligands of silicon increases steric congestion upo
Access to polysubstituted naphthalenes and anthracenes via a retro-Diels–Alder reaction
Akin, Esra Turan,Erdogan, Musa,Dastan, Arif,Saracoglu, Nurullah
, p. 5537 - 5546 (2017/08/22)
Naphthalene and anthracene nuclei are present in several natural and synthetic compounds. Due to their unique physical and chemical properties, access to functionalized naphthalenes and anthracenes has attracted the attention of both synthetic and medicinal chemists over the decades. In this study, successive Diels–Alder/retro-Diels–Alder reactions of dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate with various bicyclic alkenes in one pot to yield naphthalene and anthracene derivatives are reported. Using anti- and syn-cyclotrimers derived from the cyclotrimerization of benzobarrelene as alkene partner enabled efficient synthesis of trinaphthylene.
MULTICYCLIC AROMATIC COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
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Paragraph 0155; 0160-0161, (2017/04/21)
The present specification describes a multicyclic aromatic ring compound having a novel structure and an organic light emitting device using the same.
Dinaphthopentalenes: Pentalene derivatives for organic thin-film transistors
Kawase, Takeshi,Fujiwara, Takeru,Kitamura, Chitoshi,Konishi, Akihito,Hirao, Yasukazu,Matsumoto, Kouzou,Kurata, Hiroyuki,Kubo, Takashi,Shinamura, Shoji,Mori, Hiroki,Miyazaki, Eigo,Takimiya, Kazuo
supporting information; experimental part, p. 7728 - 7732 (2011/01/08)
Extended π system: A nickel(0)-mediated reaction afforded dinaphthopentalene derivatives, whose electronic and electrochemical properties depend on the fusion patterns. Very high hole mobility was observed for an amorphous material, and the compounds are
