1259986-98-5Relevant academic research and scientific papers
Comparative Analysis of Fluorine-Directed Glycosylation Selectivity: Interrogating C2 [OH → F] Substitution in d- Glucose and d- Galactose
Santschi, Nico,Gilmour, Ryan
, p. 6983 - 6987 (2015)
The influence of C2 [OH → F] substitution on the stereochemical course of chemical glycosylation was interrogated in both D-glucose and its C4 epimer D-galactose. Molecular editing at C2 and configurational inversion at C4 were simultaneously investigated
Fluorine-directed glycosylation
Bucher, Christoph,Gilmour, Ryan
supporting information; experimental part, p. 8724 - 8728 (2011/01/06)
Everything's under control: A stabilizing fluorine electrostatic interaction has been exploited to control oxonium ion conformation in 2-fluoropyranose derivatives (see scheme). When matched with the inductive nature of the protecting groups, the glycosyl
