126002-56-0Relevant academic research and scientific papers
Reduction of activated thiopyridyl compounds by zinc metal
Boivin, Jean,Lallemand, Jean-Yves,Schmitt, Andreas,Zard, Samir Z.
, p. 7243 - 7246 (1995)
Starting from thiopyridyl compounds bearing a radical stabilizing group in α-position to the thiopyridyl moiety, the thiopyridyl group can be easily removed upon reduction by zinc metal in acetic acid.
Decarboxylative radical addition to vinylsulphones and vinylphosphonium bromide: Some further novel transformations of geminal (pyridine-2-thiyl) phenylsulphones
Barton,Boivin,Crepon nee da Silva,Sarma,Togo,Zard
, p. 7091 - 7108 (2007/10/02)
Irradiation of O-acyl derivatives 1 of N-hydroxy-2-thiopyridone with visible light in the presence of phenyl vinyl sulphone or vinyl triphenylphosphonium bromide leads to the corresponding adducts 8 and 9 which can undergo a wide variety of further transformations.
SOME FURTHER NOVEL TRANSFORMATIONS OF GEMINAL (PYRIDINE-2-THIYL) PHENYLSULPHONES
Barton, Derek H. R.,Boivin, Jean,Sarma, Jadab,Silva, Elisabeth da,Zard, Samir Z.
, p. 4237 - 4240 (2007/10/02)
Geminal (pyridine-2-thiyl) phenylsulphones, obtained by decarboxylative radical addition of O-acyl derivatives of N-hydroxy-2-thiopyridone onto phenyl vinyl sulphone, undergo a wide variety of further transformations when subjected to sodium telluride or to organoaluminum reagents.
