1260110-64-2Relevant academic research and scientific papers
Comparison of coordination mode of some biphosphine ligands in cyclometalated organoplatinum(II) complexes
Esmaeilbeig, Ahmad R.,Haghighi, Mohsen Golbon,Nikahd, Sahebeh,Hashemi, Sara,Mosarezaee, Mohammad,Rashidi, Mehdi,Nabavizadeh, S. Masoud
supporting information, p. 93 - 100 (2014/03/21)
The reaction of the cyclometalated complexes [PtR(?N)(SMe 2)], 1, in which R is Me or 4-MeC6H4, and ?N is either ppy (deprotonated 2-phenylpyridine) or bhq (deprotonated benzo-h-quinoline), with 1,2-bis[bis(pentafluorophen
Cyclometalated organoplatinum(ii) complexes: First example of a monodentate benzo[h]quinolyl ligand and a complex with bridging bis(diphenylphosphino) ethane
Haghighi, Mohsen Golbon,Rashidi, Mehdi,Nabavizadeh, S. Masoud,Jamali, Sirous,Puddephatt, Richard J.
, p. 11396 - 11402 (2011/02/16)
The cyclometalated complexes [Pt(ppy)R(SMe2)] or [Pt(bhq)R(SMe2)], where ppyH = 2-phenylpyridine, bhqH = benzo[h]quinoline and R = methyl or p-tolyl, react with bis(diphenylphosphino) ethane, dppe, in a 1:1 ratio to give the corresponding complexes [Pt(κ1-C-ppy)R(dppe)] or [Pt(κ1-C-bhq)R(dppe)] , in which the ppy or bhq ligands are monodentate and dppe is chelating. The similar reaction in a 2:1 ratio gives the binuclear complexes [{Pt(ppy)R} 2(μ-dppe)] or [{Pt(bhq)R}2(μ-dppe)], in which the dppe ligands are in the unusual bridging bidentate bonding mode.
