1260118-78-2

Upstream product

• 16212-05-8 (allylsulfonyl)benzene 
• 10365-98-7 3-methoxyphenylboronic acid 
• 591-31-1 3-methoxy-benzaldehyde 
• 1417801-93-4 (E)-1-methoxy-3-(3-(phenylsulfonyl)allyl)benzene 
• 65292-99-1 2-(3-methoxyphenyl)acetaldehyde 

Downstream Products

• 1417801-88-7 2-(4-methoxy-2-(3-(phenylsulfonyl)propyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1417801-89-8 5-isopropoxy-2,6-dimethoxy-3-(4-methoxy-2-(3-(phenylsulfonyl)propyl)phenyl)-9,10-dihydrophenanthrene 
• 1417801-95-6 5-isopropoxy-2,6-dimethoxy-3-(4-methoxy-2-(3-(phenylsulfonyl)but-3-en-1-yl)phenyl)-9,10-dihydrophenanthrene 
• 1417801-96-7 4-((3,7-dimethoxy-6-(4-methoxy-2-(3-(phenylsulfonyl)but-3-en-1-yl)phenyl)-9,10-dihydrophenanthren-4-yl)oxy)-2H-pyran-2-one 
• 1417801-94-5 1-bromo-4-methoxy-2-(3-(phenylsulfonyl)propyl)benzene 
• 1417801-97-8 3,7-dimethoxy-6-(4-methoxy-2-(3-(phenylsulfonyl)but-3-en-1-yl)phenyl)-9,10-dihydrophenanthren-4-ol 

Relevant academic research and scientific papers

Total synthesis of (±)-cavicularin: Control of pyrone diels-alder regiochemistry using isomeric vinyl sulfones

An intramolecular pyrone Diels-Alder reaction-elimination retro-Diels-Alder cascade of a vinyl sulfone was used in the synthesis of cavicularin, a molecule possessing conformational chirality. The vinyl sulfone substitution pattern allowed for regiocontrol in the Diels-Alder cascade event.

Linear-selective rhodium(I)-catalyzed addition of arylboronic acids to allyl sulfones

One step further: The rhodium(I)-catalyzed addition of readily available arylboronic acids to allyl sulfones affords the linear (formal) hydroarylated products in good yields and excellent regioselectivities. The reaction broadens the scope of unactivated