1260153-58-9Relevant academic research and scientific papers
Spin-adduct of the P4?- radical anion during the electrochemical reduction of white phosphorus
Kadirov,Budnikova,Kholin,Valitov,Krasnov,Gryaznova,Sinyashin
, p. 466 - 468 (2010)
The radical anion P4?- was detected and identified by the ESR method as a spin-adduct with nitrone during the electrochemical reduction of white phosphorus in the presence of a spin trap, viz., α-phenyl-N-tert-butylnitrone, in a special electrolysis cell with a helical platinum working electrode in the potentiostatic mode. The character of the behavior of P4?- and the spin trap during electrochemical reduction was monitored by cyclic voltammetry directly in the electrolysis cell, and the spin-adduct formed was detected by ESR.
