1260160-56-2Relevant academic research and scientific papers
Heteroatom nucleophile induced C-C fragmentations to access functionalized allenes
Saget, Tanguy,Cramer, Nicolai
scheme or table, p. 205 - 207 (2012/07/28)
The rich structural and reactivity profile of allenes render them versatile synthetic intermediates. However, application of allenes in organic chemistry is often attenuated by inconvenient methods of preparation. Herein we present an operationally simple
Heteroatom-nucleophile-induced C - C fragmentations: Synthesis of allenes and entry to domino reactions
Saget, Tanguy,Cramer, Nicolai
supporting information; experimental part, p. 8962 - 8965 (2011/02/24)
Blessed are the piece-makers: Heteroatom nucleophiles (NuH) induce Grob-type fragmentations of vinyl triflates under mild conditions and provide-allene-functionalized carboxylic acid derivatives. These products are a versatile starting point for domino an
