1260180-26-4Relevant articles and documents
Stereoselective synthesis of 4-substituted 4-hydroxypiperidines via epoxidation-ring opening of 4-methylenepiperidines
McKay, Victoria A.,Thompson, Sarah J.,Tran, Phuong Minh,Goodall, Kirsten J.,Brimble, Margaret A.,Barker, David
scheme or table, p. 2631 - 2635 (2010/12/18)
Reaction of 9-methylene-3-azabicyclo[3.3.1]nonanes with trifluoroperacetic acid results in stereoselective epoxidation to give the syn-epoxide. Intermolecular hydrogen bonding between the protonated tertiary amine and the peracid is responsible for the hi