1260249-89-5Relevant academic research and scientific papers
Highly enantioselective organocatalysis of the Michael addition of benzyloxyacetaldehyde to nitroolefins
Burugupalli, Sripragna,Qiao, Yupu,Headley, Allan D.
, p. 1608 - 1611 (2017)
A novel category of di(N,N-dimethylbenzylamine)prolinol silyl ether catalyst, which when used in conjunction with an acidic co-catalyst, generates an ammonium salt supported organocatalyst. This catalytic system is shown to be very effective for the Micha
Enantioselective organocatalytic michael additions of oxyacetaldehydes to nitroolefins
Polackova, Viera,Marak, Jozef,Kaniansky, Dusan,Sebesta, Radovan,Toma, A. Stefan
experimental part, p. 6430 - 6435 (2011/02/21)
Alkyl and aryloxyacetaldehydes add enantioselectively to various nitroalkenes. Addition products were isolated in good yield and high enantiomeric purity (up to 96 ee) but only mediocre syn/anti ratios were achieved. The course of the reaction was investi
