1260404-97-4Relevant academic research and scientific papers
Direct arylation of oligonaphthalenes using PIFA/BF3· Et2O: From double arylation to larger oligoarene products
Guo, Wusheng,Faggi, Enrico,Sebastian, Rosa M.,Vallribera, Adelina,Pleixats, Roser,Shafir, Alexandr
, p. 8169 - 8175 (2013/09/12)
Direct dehydrogenative coupling between the linear ter- and quaternaphthalenes and substituted benzenes was achieved under the Kita conditions using the hypervalent PIFA/BF3 reagent. Products resulting from either the double arylation of the naphthalenic substrate or the formal dimerizative arylation have been prepared. For example, in the latter mode, ternaphthalene was converted into a series of linear octiarenes (counting the capping Ar). The process represents an alternative to the cross-coupling methodologies employed in related syntheses and proceeds via a selective functionalization of six relatively inert aromatic CH bonds.
Direct assembly of polyarenes via C-C coupling using PIFA/BF 3?Et2O
Faggi, Enrico,Sebastian, Rosa M.,Pleixats, Roser,Vallribera, Adelina,Shafir, Alexandr,Rodriguez-Gimeno, Alejandra,Ramirez De Arellano, Carmen
supporting information; experimental part, p. 17980 - 17982 (2011/02/28)
Direct oxidative Kita-type coupling between naphthalene and substituted benzenes was found to proceed via four-component coupling, leading to a linear tetraarene with a binaphthalene core. The methodology was extendable to the coupling of unfunctionalized
